Meerwein-Ponndorf-Verley Reduction and Oppenauer Oxidation Catalyzed by Heterogeneous Catalysts

  • M. Bartosova Department of Organic Technology, Institute of Chemical Technology, Prague,
  • L. Cerveny Department of Organic Technology, Institute of Chemical Technology, Prague,
  • B. Wichterlova Jaroslav Heyrovsky Institute of Physical Chemistry, Academy of Sciences of the Czech Republic, Prague

Abstrakt

The article summarizes literature findings on Meerwein-Ponndorf-Verley oxidations on heterogeneous catalysts. including amorphous metallic oxides and zeolites that exhibit surface basicity or Lewis acidity. Attention is primarily focused on catalytic properties of high-silicate zeolites of ß-structure based on alumosilicates and titanosilicates. The reaction mechanism and high cis stereoselectivity of the catalysts are discussed. The reactions find use in the field of specialty chemicals.
Publikované
2001-06-15
Sekce
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